Complete Differences Between Pure Zirconium Crucibles (Zr702/R60702) and Zirconium Alloy Crucibles (Mainstream Zr705/R60705) In the industry, pure zirconium crucibles are defined as industrial pure zirconium Zr702; zirconium alloy crucibles are defined as zirconium-niobium alloy Zr705 (containing 2.0~3.0% Nb). The two differ significantly in raw materials, strength, purity, corrosion resistance, and applicable experimental scenarios.
I. Core Differences Between Composition and Grade
1. Pure Zirconium Crucible Zr702 (UNS R60702)
Definition: Industrially pure zirconium, Zr+Hf≥99.2%, only trace impurities, no alloying elements
Composition: Contains only trace amounts of Fe, Cr, O, C, N; Hf≤4.5%, niobium and tin are not present
Purity Advantage: Minimal matrix impurities, almost no foreign element contamination of the sample when smelting active metals
2. Zirconium Alloy Crucible Zr705 (UNS R60705)
Definition: Zirconium-niobium alloy, intentionally reinforced with 2.0%~3.0% metallic niobium
Composition: Zr balance + 2~3% Nb, impurity limit slightly higher than Zr702
Disadvantage: Contains niobium, cannot be used for high-purity experiments requiring absolutely niobium-free impurities.
II. Comparison of Mechanical and High-Temperature Properties
|
Performance Items |
Pure Zirconium Zr702 Crucible | Zirconium Alloy Zr705 Crucible |
| Room Temperature Strength | Moderate, tensile strength approximately 450MPa, relatively soft texture, excellent plasticity, easily spin-formed into small crucibles. Significantly improved | strength, tensile strength ≈600MPa, yield strength nearly twice that of pure zirconium, higher rigidity. |
| High Temperature Creep Resistance | Prone to slight deformation under long-term high-temperature load; large-volume thin-walled crucibles are prone to bulging at the bottom. | High-Temperature Rigidity: Highly rigid at high temperatures, resistant to creep and deformation; larger sizes and thicker walls are more durable. |
| Impact/Abrasion Resistance | Moderate; easily dented by impacts. | Better hardness and abrasion resistance; longer lifespan with repeated filling and erosion. |
| Processing and Forming | Good ductility; ideal for laboratory crucibles (5~200ml); excellent weldability. | Lower plasticity; more difficult to process; higher cost for the same size. |
| Ultimate Operating Temperature | Vacuum/Inert long-term ≤1600℃, short-term 1700℃. | Ultimate temperature limits are basically the same. At 1600℃, the deformation is much smaller than that of pure zirconium. |
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Comparison table of mechanical properties of industrial pure zirconium crucibles and zirconium-niobium alloy crucibles
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III. Chemical Corrosion Resistance & Sample Contamination Differences (Core Selection Criteria for Laboratories)
Pure Zirconium Zr702: Stronger resistance to strong acids (hydrochloric acid, dilute sulfuric acid, hydrofluoric acid systems), molten alkalis, and halogen corrosion.
No niobium precipitation; does not introduce Nb impurities when melting Ti, Zr, rare earths, or high-purity metals.
Suitable for high-purity materials, trace element analysis, semiconductors, and rare earth purification experiments.
Zrconium Alloy Zr705: Corrosion resistance to conventional acids and alkalis is close to that of pure zirconium, but slightly weaker in high-concentration sulfuric acid and chloride media.
The matrix contains niobium; trace amounts of niobium impurities may dissolve in the high-temperature melt, contaminating high-purity samples.
Not suitable for the preparation of materials with strict Nb content limitations.
IV. Molding, Wall Thickness, and Service Life
Small Laboratory Crucibles (5~200ml)
Zr702: Standard Wall Thickness 2-3mm thick, spun in one piece, smooth inner wall, lower price, most common on the market.
Zr705: Requires thicker wall for the same volume, higher processing cost, rarely used for small sizes.
Medium to large industrial crucibles (500ml~10L and above)
Zr702: Prone to bottom bulging under long-term high temperature and pressure, requires thickening to 5-8mm.
Zr705: Stronger rigidity for the same wall thickness, less prone to deformation, service life increased by over 40% after repeated high-temperature melting.
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